64DD wouldn't get disc rot, it would get bit rot, since the DD disks weren't optical discs.
Yeah, Discs are supposed to generally have a life span of 25 or so years than they start corrupting themselves or something, this also has to do with sunlight, moisture, and other variables. This is one of the reasons I don't bother collecting for Disc based consoles because in addition to moving parts and finicky lasers you have fragile rotting discs to worry about (and those crappy jewel cases). This is also why I stand 100% disc drive replacement flash solutions for consoles.
On another note the brand of disc probably influences the rate of rotting, discs made specifically for archival purposes probably last longer, but they cost more so I doubt anyone in the game business used them. Supposedly the best solution to bit rod are "M-Discs" they have some kind of silica(rock) on them that's in theory supposed to last a super long time.
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