Originally posted by: Frigusoris
Heat = expand. I can't explain how it would help without getting hot enough to melt the plastic, but just maybe it gets out the ground in dust and dirt by expanding the plastic and to a lesser degree the metal pins to release all the pent up gunk. I'm very tempted to try, but I know for a fact the one I'm thinking of trying it on is "genied out" from the years before I knew the game genie screwed up your PIN connector. When you're young, you do what you gotta to play games, and the only way mine would work, and still the only way it works without LOADS of trys, is to use the game genie. Doesn't help my "NES" is just the bare board screwed into the bottom of a nes case (long story)...
I think it's just cleaning the contacts
There is no way that boiling water is going to reach the yield temperature of the pins, and they're definitely not going to "tighten up" naturally. It would require forcibly bending them back into the place. Once they've bent out of position that is the new unloaded position of the metal.